Note: Click on any image for a larger view of that particular image.
Locate the icon of the program that you want to launch faster. Then right click on it and select Properties.
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Then put the mouse cursor in the Shortcut Key box (click on the word None )
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Choose a key combination that you want to use as a shortcut key using any combination of CONTROL, ALT and/or SHIFT keys along with any regular keyboard character (alphanumeric). Then, on your keyboard, hit that key combination. You will see your key combinations appear as you press them
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Then Click Apply and you are done. You can test it out immediately by just hitting the same key combination. If your program opens, then it is working.